Abstract
Large-diameter (up to 3-inch), n-type ZnO boules grown by a new vapor-phase transport method were studied by temperature-dependent Hall-effect (TDH) and photoluminescence (PL) measurements. From fits to the TDH data, the dominant donor has a concentration ND of about 1 × 1017 cm-3 and an energy of about 60 meV, close to the expected hydrogenic value, whereas the total acceptor concentration NA is much lower, about 2 × 1015 cm-3. The 2-K PL data include a series of at least seven sharp lines over the energy range 3.356 - 3.366 eV, and from polarization, magnetic-field, and annealing (up to 1000°C) experiments, these lines are interpreted as donor-bound excitons associated with donor complexes having different spacings between the atomic species. Electron-irradiation experiments show an electrical and optical threshold, attributed to Zn displacements, at an electron bombardment energy of about 1.3 MeV. The irradiation creates acceptors and destroys shallow donors, but these effects are produced at much lower rates than those found in most other common semiconductor materials, such as Si, GaAs, and GaN.
Original language | English |
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Title of host publication | Semiconducting and Insulating Materials 1998. Proceedings of the 10th Conference on Semiconducting and Insulating Materials (SIMC-X) (Cat. No.98CH36159) |
Publisher | IEEE |
Pages | 301-304 |
Number of pages | 4 |
ISBN (Print) | 0-7803-4354-9 |
DOIs | |
State | Published - 1999 |
Event | Proceedings of the 1998 10th Conference on Semiconducting and Insulating Materials (SIMC-X) - Berkeley, CA, USA Duration: Jun 1 1998 → Jun 5 1998 |
Conference
Conference | Proceedings of the 1998 10th Conference on Semiconducting and Insulating Materials (SIMC-X) |
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City | Berkeley, CA, USA |
Period | 6/1/98 → 6/5/98 |
ASJC Scopus Subject Areas
- General Engineering
Keywords
- Zinc oxide
- Photoluminescence
- Optical polarization
- Annealing
- Excitons
- Atom optics
- Electron optics
- Semiconductor materials
- Gallium arsenide
- Gallium nitride
Disciplines
- Electrical and Computer Engineering
- Atomic, Molecular and Optical Physics