Excess second virial coefficients for (benzene + n-hexane) and (cyclohexane + n-hexane)

R. Battino; R. Malhotra; P. J. McElroy; A. G. Williamson

doi:10.1016/0021-9614(83)90106-4

Excess second virial coefficients for (benzene + n-hexane) and (cyclohexane + n-hexane)

R. Battino, R. Malhotra, P. J. McElroy, A. G. Williamson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

For (benzene + n-hexane) and (cyclohexane + n-hexane) measurements are reported of the pressure change on mixing and the excess second virial coefficient ε{lunate}12 calculated therefrom. Measurements at the following temperatures are reported: 298.15, 323.15, 373.15, and 398.15 K. The correlations due to Tsonopoulos and to Hayden and O'Connell are typically in error by 50 cm3·mol-1 or more; further development of the latter correlation appears justified.

Original language	English
Pages (from-to)	83-88
Number of pages	6
Journal	The Journal of Chemical Thermodynamics
Volume	15
Issue number	1
DOIs	https://doi.org/10.1016/0021-9614(83)90106-4
State	Published - Jan 1983

ASJC Scopus Subject Areas

Atomic and Molecular Physics, and Optics
General Materials Science
Physical and Theoretical Chemistry

Disciplines

Chemistry

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10.1016/0021-9614(83)90106-4

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author = "R. Battino and R. Malhotra and McElroy, {P. J.} and Williamson, {A. G.}",

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AU - Battino, R.

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AU - McElroy, P. J.

AU - Williamson, A. G.

PY - 1983/1

Y1 - 1983/1

N2 - For (benzene + n-hexane) and (cyclohexane + n-hexane) measurements are reported of the pressure change on mixing and the excess second virial coefficient ε{lunate}12 calculated therefrom. Measurements at the following temperatures are reported: 298.15, 323.15, 373.15, and 398.15 K. The correlations due to Tsonopoulos and to Hayden and O'Connell are typically in error by 50 cm3·mol-1 or more; further development of the latter correlation appears justified.

AB - For (benzene + n-hexane) and (cyclohexane + n-hexane) measurements are reported of the pressure change on mixing and the excess second virial coefficient ε{lunate}12 calculated therefrom. Measurements at the following temperatures are reported: 298.15, 323.15, 373.15, and 398.15 K. The correlations due to Tsonopoulos and to Hayden and O'Connell are typically in error by 50 cm3·mol-1 or more; further development of the latter correlation appears justified.

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ER -

Excess second virial coefficients for (benzene + n-hexane) and (cyclohexane + n-hexane)

Abstract

ASJC Scopus Subject Areas

Disciplines

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