Solubility of Gases in Liquids. 15. High-Precision Determination of Henry Coefficients for Carbon Monoxide in Liquid Water at 278 to 323 K

Timothy R. Rettich; Rubin Battino; Emmerich Wilhelm

doi:10.1002/bbpc.198200051

Solubility of Gases in Liquids. 15. High-Precision Determination of Henry Coefficients for Carbon Monoxide in Liquid Water at 278 to 323 K

Timothy R. Rettich, Rubin Battino, Emmerich Wilhelm

Wright State University

Research output: Contribution to journal › Article › peer-review

Abstract

The solubility of carbon monoxide in pure liquid water was measured in the pressure range 60 to 110 kPa and the temperature range 278 to 323 K with a high-precision apparatus of the Benson-Krause type. These data are used to derive Henry coefficients H _{2, 1} ( T, P _{s, 1} ), the temperature dependence of which is accounted for by both a Clarke-Glew type fitting equation and a power series in T ⁻¹ . The imprecision of our measurements is characterized by an average deviation of H _{2, 1} ( T, P _{s, 1} ) from these smoothing equations of about ±0.04%. From the temperature variation of H _{2, 1} ( T, P _{s, 1} ) the partial molar quantities pertaining to the solution process (such as standard changes in enthalpy and heat capacity) are obtained. In addition, Ostwald coefficients are given in tabular form at rounded temperatures. Experimental results are compared with values calculated via scaled particle theory.

Original language	American English
Journal	Berichte der Bunsengesellschaft für Physikalische Chemie
Volume	86
DOIs	https://doi.org/10.1002/bbpc.198200051
State	Published - Dec 1 1982

Keywords

Henry-Koeffizienten
Lösungen
Phasengleichgewichte
Thermodynamik

Disciplines

Chemistry
Physical Sciences and Mathematics

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10.1002/bbpc.198200051License: Unspecified

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title = "Solubility of Gases in Liquids. 15. High-Precision Determination of Henry Coefficients for Carbon Monoxide in Liquid Water at 278 to 323 K",

abstract = " The solubility of carbon monoxide in pure liquid water was measured in the pressure range 60 to 110 kPa and the temperature range 278 to 323 K with a high-precision apparatus of the Benson-Krause type. These data are used to derive Henry coefficients H 2, 1 ( T, P s, 1 ), the temperature dependence of which is accounted for by both a Clarke-Glew type fitting equation and a power series in T −1 . The imprecision of our measurements is characterized by an average deviation of H 2, 1 ( T, P s, 1 ) from these smoothing equations of about ±0.04%. From the temperature variation of H 2, 1 ( T, P s, 1 ) the partial molar quantities pertaining to the solution process (such as standard changes in enthalpy and heat capacity) are obtained. In addition, Ostwald coefficients are given in tabular form at rounded temperatures. Experimental results are compared with values calculated via scaled particle theory.",

keywords = "Henry-Koeffizienten, L{\"o}sungen, Phasengleichgewichte, Thermodynamik",

author = "Rettich, {Timothy R.} and Rubin Battino and Emmerich Wilhelm",

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doi = "10.1002/bbpc.198200051",

language = "American English",

volume = "86",

journal = "Berichte der Bunsengesellschaft f{\"u}r Physikalische Chemie",

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T1 - Solubility of Gases in Liquids. 15. High-Precision Determination of Henry Coefficients for Carbon Monoxide in Liquid Water at 278 to 323 K

AU - Rettich, Timothy R.

AU - Battino, Rubin

AU - Wilhelm, Emmerich

PY - 1982/12/1

Y1 - 1982/12/1

N2 - The solubility of carbon monoxide in pure liquid water was measured in the pressure range 60 to 110 kPa and the temperature range 278 to 323 K with a high-precision apparatus of the Benson-Krause type. These data are used to derive Henry coefficients H 2, 1 ( T, P s, 1 ), the temperature dependence of which is accounted for by both a Clarke-Glew type fitting equation and a power series in T −1 . The imprecision of our measurements is characterized by an average deviation of H 2, 1 ( T, P s, 1 ) from these smoothing equations of about ±0.04%. From the temperature variation of H 2, 1 ( T, P s, 1 ) the partial molar quantities pertaining to the solution process (such as standard changes in enthalpy and heat capacity) are obtained. In addition, Ostwald coefficients are given in tabular form at rounded temperatures. Experimental results are compared with values calculated via scaled particle theory.

AB - The solubility of carbon monoxide in pure liquid water was measured in the pressure range 60 to 110 kPa and the temperature range 278 to 323 K with a high-precision apparatus of the Benson-Krause type. These data are used to derive Henry coefficients H 2, 1 ( T, P s, 1 ), the temperature dependence of which is accounted for by both a Clarke-Glew type fitting equation and a power series in T −1 . The imprecision of our measurements is characterized by an average deviation of H 2, 1 ( T, P s, 1 ) from these smoothing equations of about ±0.04%. From the temperature variation of H 2, 1 ( T, P s, 1 ) the partial molar quantities pertaining to the solution process (such as standard changes in enthalpy and heat capacity) are obtained. In addition, Ostwald coefficients are given in tabular form at rounded temperatures. Experimental results are compared with values calculated via scaled particle theory.

KW - Henry-Koeffizienten

KW - Lösungen

KW - Phasengleichgewichte

KW - Thermodynamik

UR - https://corescholar.libraries.wright.edu/chemistry/155

U2 - 10.1002/bbpc.198200051

DO - 10.1002/bbpc.198200051

M3 - Article

VL - 86

JO - Berichte der Bunsengesellschaft für Physikalische Chemie

JF - Berichte der Bunsengesellschaft für Physikalische Chemie

ER -

Solubility of Gases in Liquids. 15. High-Precision Determination of Henry Coefficients for Carbon Monoxide in Liquid Water at 278 to 323 K

Abstract

Keywords

Disciplines

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