TY - JOUR
T1 - Solubility of Gases in Liquids. 19. Solubility of He, Ne, Ar, Kr, Xe, N2, O2, CH4, CF4, and SF6 in Normal 1-Alkanols n-C1H2l+1OH (1 ≤ 1 ≤ 11) at 298.15 K
AU - Bo, Shiqing
AU - Battino, Rubin
AU - Wilhelm, Emmerich
PY - 1993/10/1
Y1 - 1993/10/1
N2 - The Ostwald coefficients L2,1 of He, Ne, Ar, Kr, Xe, N2, O2, CH4, CF4, and SF6 dissolved in several homologous alkan-1-ols, n-ClH2l+1OH, 1 ≤ l ≤ 11, have been determined at 298.15 K and atmospheric pressure. Altogether, 102 gas/liquid systems were investigated. The medium precision apparatus (about ±0.5%) was of the Ben-Naim/Baer type, similar to our recently published design. Data reduction is presented in some detail, including the estimation of auxiliary quantities, such as second virial coefficients and partial molar volumes at infinite dilution. The effect of chain length l is shown, and several correlations between L2,1 (and/or the derived Henry fugacity H2,1) and appropriate molecular and/or bulk properties of the gases and solvents are discussed.
AB - The Ostwald coefficients L2,1 of He, Ne, Ar, Kr, Xe, N2, O2, CH4, CF4, and SF6 dissolved in several homologous alkan-1-ols, n-ClH2l+1OH, 1 ≤ l ≤ 11, have been determined at 298.15 K and atmospheric pressure. Altogether, 102 gas/liquid systems were investigated. The medium precision apparatus (about ±0.5%) was of the Ben-Naim/Baer type, similar to our recently published design. Data reduction is presented in some detail, including the estimation of auxiliary quantities, such as second virial coefficients and partial molar volumes at infinite dilution. The effect of chain length l is shown, and several correlations between L2,1 (and/or the derived Henry fugacity H2,1) and appropriate molecular and/or bulk properties of the gases and solvents are discussed.
KW - Solubility
KW - Gases
UR - http://www.scopus.com/inward/record.url?scp=0027677451&partnerID=8YFLogxK
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UR - https://corescholar.libraries.wright.edu/chemistry/144
U2 - 10.1021/je00012a035
DO - 10.1021/je00012a035
M3 - Article
AN - SCOPUS:0027677451
SN - 0021-9568
VL - 38
SP - 611
EP - 616
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 4
ER -