The Solubility of Gases in Liquids 6. Solubility of Nsub2/sub, Osub2/sub, CO, COsub2/sub, CHsub4/sub, and CFsub4/sub in Methylcyclohexane and Toluene at 283 to 313 K

Larry R. Field; Emmerich Wilhelm; Rubin Battino

doi:10.1016/0021-9614(74)90175-X

The Solubility of Gases in Liquids 6. Solubility of Nsub2/sub, Osub2/sub, CO, COsub2/sub, CHsub4/sub, and CFsub4/sub in Methylcyclohexane and Toluene at 283 to 313 K

Larry R. Field, Emmerich Wilhelm, Rubin Battino

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The solubilities of N2, O2, CO, CO2, CH4, and CF4 in methylcyclohexane and toluene have been determined at 1 atm pressure in the range 283 to 313 K. The solubility, Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated from the experimental results. These values have been compared with the results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally good. This theory is also used to discuss the different behavior of alicyclic and aromatic solvents with respect to gas solubility.

Original language	English
Pages (from-to)	237-243
Number of pages	7
Journal	The Journal of Chemical Thermodynamics
Volume	6
Issue number	3
DOIs	https://doi.org/10.1016/0021-9614(74)90175-X https://doi.org/10.1016/0021-9614(74)90175-X
State	Published - Mar 1974

ASJC Scopus Subject Areas

Atomic and Molecular Physics, and Optics
General Materials Science
Physical and Theoretical Chemistry

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Chemistry
Physical Sciences and Mathematics

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title = "The Solubility of Gases in Liquids 6. Solubility of Nsub2/sub, Osub2/sub, CO, COsub2/sub, CHsub4/sub, and CFsub4/sub in Methylcyclohexane and Toluene at 283 to 313 K",

abstract = "The solubilities of N2, O2, CO, CO2, CH4, and CF4 in methylcyclohexane and toluene have been determined at 1 atm pressure in the range 283 to 313 K. The solubility, Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated from the experimental results. These values have been compared with the results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally good. This theory is also used to discuss the different behavior of alicyclic and aromatic solvents with respect to gas solubility.",

author = "Field, {Larry R.} and Emmerich Wilhelm and Rubin Battino",

year = "1974",

month = mar,

doi = "10.1016/0021-9614(74)90175-X",

language = "English",

volume = "6",

pages = "237--243",

journal = "The Journal of Chemical Thermodynamics",

issn = "0021-9614",

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T1 - The Solubility of Gases in Liquids 6. Solubility of Nsub2/sub, Osub2/sub, CO, COsub2/sub, CHsub4/sub, and CFsub4/sub in Methylcyclohexane and Toluene at 283 to 313 K

AU - Field, Larry R.

AU - Wilhelm, Emmerich

AU - Battino, Rubin

PY - 1974/3

Y1 - 1974/3

N2 - The solubilities of N2, O2, CO, CO2, CH4, and CF4 in methylcyclohexane and toluene have been determined at 1 atm pressure in the range 283 to 313 K. The solubility, Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated from the experimental results. These values have been compared with the results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally good. This theory is also used to discuss the different behavior of alicyclic and aromatic solvents with respect to gas solubility.

AB - The solubilities of N2, O2, CO, CO2, CH4, and CF4 in methylcyclohexane and toluene have been determined at 1 atm pressure in the range 283 to 313 K. The solubility, Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated from the experimental results. These values have been compared with the results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally good. This theory is also used to discuss the different behavior of alicyclic and aromatic solvents with respect to gas solubility.

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JO - The Journal of Chemical Thermodynamics

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The Solubility of Gases in Liquids 6. Solubility of Nsub2/sub, Osub2/sub, CO, COsub2/sub, CHsub4/sub, and CFsub4/sub in Methylcyclohexane and Toluene at 283 to 313 K

Abstract

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