The solubility of gases in liquids 8. Solubility of He, Ne, Ar, Kr, CO2, CH4, CF4, and SF6 in o-, m-, and p-xylene at 283 to 313 K

Joseph E. Byrne; Rubin Battino; Emmerich Wilhelm

doi:10.1016/0021-9614(75)90184-6

The solubility of gases in liquids 8. Solubility of He, Ne, Ar, Kr, CO₂, CH₄, CF₄, and SF₆ in o-, m-, and p-xylene at 283 to 313 K

Joseph E. Byrne
, Rubin Battino
, Emmerich Wilhelm

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The solubilities of He, Ne, Ar, Kr, CO2, CH4, CF4, and SF6 in the three isomeric xylenes have been determined at atmospheric pressure in the range 283 to 313 K. From the experimental results partial molar Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated. These values have been compared with results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally satisfactory.

Original language	English
Pages (from-to)	515-522
Number of pages	8
Journal	The Journal of Chemical Thermodynamics
Volume	7
Issue number	6
DOIs	https://doi.org/10.1016/0021-9614(75)90184-6
State	Published - Jun 1 1975

ASJC Scopus Subject Areas

Atomic and Molecular Physics, and Optics
General Materials Science
Physical and Theoretical Chemistry

Keywords

Gases

Disciplines

Chemistry

Access to Document

10.1016/0021-9614(75)90184-6

Cite this

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title = "The solubility of gases in liquids 8. Solubility of He, Ne, Ar, Kr, CO2, CH4, CF4, and SF6 in o-, m-, and p-xylene at 283 to 313 K",

abstract = "The solubilities of He, Ne, Ar, Kr, CO2, CH4, CF4, and SF6 in the three isomeric xylenes have been determined at atmospheric pressure in the range 283 to 313 K. From the experimental results partial molar Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated. These values have been compared with results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally satisfactory.",

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author = "Byrne, \{Joseph E.\} and Rubin Battino and Emmerich Wilhelm",

year = "1975",

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AU - Byrne, Joseph E.

AU - Battino, Rubin

AU - Wilhelm, Emmerich

PY - 1975/6/1

Y1 - 1975/6/1

N2 - The solubilities of He, Ne, Ar, Kr, CO2, CH4, CF4, and SF6 in the three isomeric xylenes have been determined at atmospheric pressure in the range 283 to 313 K. From the experimental results partial molar Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated. These values have been compared with results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally satisfactory.

AB - The solubilities of He, Ne, Ar, Kr, CO2, CH4, CF4, and SF6 in the three isomeric xylenes have been determined at atmospheric pressure in the range 283 to 313 K. From the experimental results partial molar Gibbs energy, enthalpy, and entropy of solution for 1 atm partial pressure of gas and 298.15 K have been calculated. These values have been compared with results obtained through application of the scaled particle theory to gas solubilities. Agreement is generally satisfactory.

KW - Gases

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UR - https://corescholar.libraries.wright.edu/chemistry/129

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JF - The Journal of Chemical Thermodynamics

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