The solubility of helium, neon, argon and krypton in some hydrocarbon solvents

H. Lawrence Clever; Rubin Battino; J. H. Saylor; P. M. Gross

doi:10.1021/j150554a009

The solubility of helium, neon, argon and krypton in some hydrocarbon solvents

H. Lawrence Clever, Rubin Battino, J. H. Saylor, P. M. Gross

Research output: Contribution to journal › Article › peer-review

Abstract

The solubility of helium, neon, argon and krypton has been determined in 13 hydrocarbon solvents at three temperatures and a total pressure of one atmosphere. Heats and entropies of solution have been calculated from the linear dependence of the logarithm of the solubility with the inverse absolute temperature over the 30° temperature range and the results compared with entropies calculated from simple qualitative pictures of gas solubility. The solubilities have been correlated with various solvent properties such as surface tension, solubility parameter and empty volume.

Original language	English
Pages (from-to)	1078-1082
Number of pages	5
Journal	Journal of Physical Chemistry
Volume	61
Issue number	8
DOIs	https://doi.org/10.1021/j150554a009
State	Published - 1957
Externally published	Yes

ASJC Scopus Subject Areas

General Engineering
Physical and Theoretical Chemistry

Disciplines

Chemistry

Access to Document

10.1021/j150554a009

Cite this

@article{23f8e4271b37475ca3eee5dc93473664,

title = "The solubility of helium, neon, argon and krypton in some hydrocarbon solvents",

abstract = "The solubility of helium, neon, argon and krypton has been determined in 13 hydrocarbon solvents at three temperatures and a total pressure of one atmosphere. Heats and entropies of solution have been calculated from the linear dependence of the logarithm of the solubility with the inverse absolute temperature over the 30° temperature range and the results compared with entropies calculated from simple qualitative pictures of gas solubility. The solubilities have been correlated with various solvent properties such as surface tension, solubility parameter and empty volume.",

author = "Clever, {H. Lawrence} and Rubin Battino and Saylor, {J. H.} and Gross, {P. M.}",

year = "1957",

doi = "10.1021/j150554a009",

language = "English",

volume = "61",

pages = "1078--1082",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

number = "8",

}

TY - JOUR

T1 - The solubility of helium, neon, argon and krypton in some hydrocarbon solvents

AU - Clever, H. Lawrence

AU - Battino, Rubin

AU - Saylor, J. H.

AU - Gross, P. M.

PY - 1957

Y1 - 1957

N2 - The solubility of helium, neon, argon and krypton has been determined in 13 hydrocarbon solvents at three temperatures and a total pressure of one atmosphere. Heats and entropies of solution have been calculated from the linear dependence of the logarithm of the solubility with the inverse absolute temperature over the 30° temperature range and the results compared with entropies calculated from simple qualitative pictures of gas solubility. The solubilities have been correlated with various solvent properties such as surface tension, solubility parameter and empty volume.

AB - The solubility of helium, neon, argon and krypton has been determined in 13 hydrocarbon solvents at three temperatures and a total pressure of one atmosphere. Heats and entropies of solution have been calculated from the linear dependence of the logarithm of the solubility with the inverse absolute temperature over the 30° temperature range and the results compared with entropies calculated from simple qualitative pictures of gas solubility. The solubilities have been correlated with various solvent properties such as surface tension, solubility parameter and empty volume.

UR - http://www.scopus.com/inward/record.url?scp=33645550900&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645550900&partnerID=8YFLogxK

U2 - 10.1021/j150554a009

DO - 10.1021/j150554a009

M3 - Article

AN - SCOPUS:33645550900

SN - 0022-3654

VL - 61

SP - 1078

EP - 1082

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 8

ER -

The solubility of helium, neon, argon and krypton in some hydrocarbon solvents

Abstract

ASJC Scopus Subject Areas

Disciplines

Access to Document

Other files and links

Cite this