TY - JOUR
T1 - Thermodynamics of binary solutions of nonelectrolytes with 2,2,4-trimethylpentane. II. Phase equilibrium study with cyclohexane and a new cooling curve apparatus
AU - Battino, Rubin
AU - Allison, George W.
PY - 1966/11/1
Y1 - 1966/11/1
N2 - The phase equilibrium of the cyclohexane-2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95° and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to II) is at -87.06° and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.
AB - The phase equilibrium of the cyclohexane-2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95° and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to II) is at -87.06° and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.
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UR - https://corescholar.libraries.wright.edu/chemistry/115
U2 - 10.1021/j100883a008
DO - 10.1021/j100883a008
M3 - Article
AN - SCOPUS:33646954586
SN - 0022-3654
VL - 70
SP - 3417
EP - 3419
JO - Journal of Physical Chemistry
JF - Journal of Physical Chemistry
IS - 11
ER -