Thermodynamics of binary solutions of nonelectrolytes with 2,2,4-trimethylpentane. II. Phase equilibrium study with cyclohexane and a new cooling curve apparatus

Rubin Battino; George W. Allison

doi:10.1021/j100883a008

Thermodynamics of binary solutions of nonelectrolytes with 2,2,4-trimethylpentane. II. Phase equilibrium study with cyclohexane and a new cooling curve apparatus

Rubin Battino
, George W. Allison

Research output: Contribution to journal › Article › peer-review

Abstract

The phase equilibrium of the cyclohexane-2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95° and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to II) is at -87.06° and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.

Original language	English
Pages (from-to)	3417-3419
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	70
Issue number	11
DOIs	https://doi.org/10.1021/j100883a008
State	Published - Nov 1 1966
Externally published	Yes

ASJC Scopus Subject Areas

General Engineering
Physical and Theoretical Chemistry

Disciplines

Chemistry
Thermodynamics

Access to Document

10.1021/j100883a008

Cite this

@article{379708f73dd04470a7a30986c32f6885,

title = "Thermodynamics of binary solutions of nonelectrolytes with 2,2,4-trimethylpentane. II. Phase equilibrium study with cyclohexane and a new cooling curve apparatus",

abstract = "The phase equilibrium of the cyclohexane-2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95° and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to II) is at -87.06° and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.",

author = "Rubin Battino and Allison, \{George W.\}",

year = "1966",

month = nov,

day = "1",

doi = "10.1021/j100883a008",

language = "English",

volume = "70",

pages = "3417--3419",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

number = "11",

}

TY - JOUR

T1 - Thermodynamics of binary solutions of nonelectrolytes with 2,2,4-trimethylpentane. II. Phase equilibrium study with cyclohexane and a new cooling curve apparatus

AU - Battino, Rubin

AU - Allison, George W.

PY - 1966/11/1

Y1 - 1966/11/1

N2 - The phase equilibrium of the cyclohexane-2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95° and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to II) is at -87.06° and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.

AB - The phase equilibrium of the cyclohexane-2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95° and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to II) is at -87.06° and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.

UR - https://www.scopus.com/pages/publications/33646954586

UR - https://www.scopus.com/pages/publications/33646954586#tab=citedBy

UR - https://corescholar.libraries.wright.edu/chemistry/115

U2 - 10.1021/j100883a008

DO - 10.1021/j100883a008

M3 - Article

AN - SCOPUS:33646954586

SN - 0022-3654

VL - 70

SP - 3417

EP - 3419

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 11

ER -

Thermodynamics of binary solutions of nonelectrolytes with 2,2,4-trimethylpentane. II. Phase equilibrium study with cyclohexane and a new cooling curve apparatus

Abstract

ASJC Scopus Subject Areas

Disciplines

Access to Document

Other files and links

Cite this